| Pos | No. | Name (s) | Club | Time |
| 1 | 35 / 36 | Gary Chambers & Blake Pond | Cyclelogic / Southfork | 20:39 |
| 2 | 33 / 34 | Stuart Hall & Mark Bird | Alltrax / RNRMCA | 20:51 |
| 3 | 25 / 26 | Tony Farnell & Mark Haynes | Penzance Wheelers | 21:49 |
| 4 | 27 / 28 | John Payne & John Fazakerly | Penzance Wheelers | 21:59 |
| 4 | 29 / 30 | Stuart Pickering & Andrew Ellis | Cyclelogic | 21:59 |
| 6 | 11 / 12 | Darren Penn & Brian Gravener | Camel Valley C&TC | 22:52 |
| 7 | 19 / 20 | Phil Walker & Damian Ayling | Penzance Wheelers | 22:55 |
| 8 | 21 / 22 | Nick Denning & Richard Taylor | Exeter Wheelers | 23:18 |
| 9 | 17 / 18 | Richard Stenton & Mike Stephens | Tavistock Wheelers / St. Austell Wheelers | 23:48 |
| 10 | 15 /16 | Tim Arkell & Angela Pike | Wolverhampton Wheelers | 24:13 |
| 11 | 5 / 6 | Mark Kurpyta & Sarah Dunn | Somerset Road Club | 24:28 |
| 12 | 7 / 8 | Cliff Morrish & Stuart West | Plymouth Corinthian CC | 25:56 |
| 13 | 1 / 2 | Andy Nosworthy & Hayley Kyte | Plymouth Corinthian CC | 26:41 |
| | 31 / 32 | Phil Borrett & Chris Halls | Bikinmotion CC | DNS |
| | 13 / 4 | Steuart Saunders & Andrew Wellings | Somerset Road Club | DNS |
| | 24 | Jonathan Philips | Mid Devon CC | DNS |
| | | | | |
| Solos | | | |
| | | | | |
| 1 | 10 | Adam Birnie | Plymouth Tri Club | 24:13 |
| 2 | 23 | Keith Watts | Mid Devon CC | 24:45 |
| 3 | 4 | Don Potter | Mid Devon CC | 25:41 |
